-linalool.gif){kind=small}
(+)-linalool
-linalyl_acetate.gif){kind=small}
(+)-linalyl acetate
bergaptene
Citrus aurantium var. bergamia (Rutaceae)
Bergamot oil, one of perfumery's most important essential oils, is expressed from the peel of the non-edible
fruits of Citrus aurantium var. bergamia, traditionally grown in the southern part of Calabria, Italy, where the soil and climatic conditions are very favourable for its cultivation. Bergamot oil is used extensively in perfumery for its sweet freshness.
Citrus oils are perfumery ingredients used in large amounts to impart fresh, sparkling notes without being overpowering. They are used at concentrations up to 25 % as a basis for the classical Eau de Colognes of the Maria Farina type like 4711 (Mülhens 1881), the modern 'Eau Fraiche'-types like Eau Sauvage (Dior 1966) or the modern classicals like Baldessarini (Boss 2002). Citrus oils harmonize very well with a large number of essential oils and synthetic odorants and are used in different proportions in nearly all modern creations. Perfumes of the so-called Chypre and Fougère types are not possible without bergamot oil [3]. Bergamot oil is also used for flavouring purposes, e.g. in Earl Grey tea and the so-called althea drops.
Bergamot oil is the only citrus oil in which (+)-limonene (26 %) is not the dominant component. The oil is rich in
(+)-linalool and (+)-linalyl acetate (> 50 %). The crude bergamot oil contains the photosensitizing furocoumarin bergaptene which must be removed before perfumery use [6].
alpha-betulenol
betulin
Birch
Betula pubescens, B. pendula, B. alba (Betulaceae)
The tender leaves of downy birch, B. pubescens, are protected
by a delicate balsam, endowing the birch moor with an enchanting fragrance
in the early springtime. Birch bud oil is rich in sesquiterpenes, among
them alpha-betulenol, alpha-betulol, germacrene D, alpha-copaene, beta-bourbonene
and aromadendrene [40] [41]. The oil has been extracted on a limited scale,
mainly for use in skin- and hair tonics.
The white colour of birch bark is due to air vacuoles in the thin-walled
cells and to the substance betulin
(up to 24 %), making the bark resistant to decay. Betulin has recently
gained interest as a chemical of potential medical applications.
The pleasant smell from burning birch wood is caused by specific compounds
from pyrolysis of betulin and birch lignins. The smell is somewhat reminiscent
of that of oakmoss.
benzaldehyde + hydrogen cyanide
Prunus amygdalis var. amara (Rosaceae)
Bitter almonds (and many other seeds of the rose family, e.g. apricot and cherry) contain amygdalin, a so-called cyanogenic glycoside. When the almonds are damaged (chewed), the amygdalin is enzymatically hydrolyzed to benzaldehyde, deadly hydrogen cyanide, and the disaccharide beta-gentiobiose. It is claimed that about 20 almonds are the lethal dose in adults, but you can't possibly eat (chew) even a single bitter almond. The chokingly powerful benzaldehyde flavour and the stunning of the tongue by hydrogen cyanide make you spit it out after a few seconds! Benzaldehyde from bitter almond was formerly used as a natural flavoring substance, but has now been largely replaced by synthetic benzaldehyde [6].
Etymology: Lat. prunus, plum tree; Gr. amygdale, almond; Lat. amarus, bitter.
examples of boronia odorants derived from carotene:
beta-ionone, 3a-hydroxymegastigm-7(E)-ene-9-one and megastigm-7(E)-ene-3,9-dione
Boronia megastigma (Rutaceae)
South-western Australia is the home of the shrubby boronia, a member of the rue family. It has 8-10 cm wide, chocolate-coloured, bell-shaped flowers emanating a fragrance somewhat between that of freesia and osmanthus. Boronia was unknown in classical European perfumery, but Tasmania now has a production of a so-called boronia absolute: The flowers are extracted with petroleum ether, yielding a waxy concentrate after evaporation. The concentrate is then extracted with alcohol, chilled, filtered and finally evaporated at reduced pressure (Rota-Vapor). Boronia absolute is used in fine perfumery and as an aroma fortifier. It has been known for several years that beta-ionone plays a major role in the fragrance of boronia. Lately it has been shown that it is followed by several similar compounds, all being metabolites of carotene. Moreover, methyl jasmonate seems to play a role in the overall fragrance [42].
4-methoxy-2-methylbutan-2-thiol
and three characteristic nitriles
Bourgeons de Cassis
Ribes nigrum, R. sanguineum (Grossulariaceae) Black
currant, Winter currant
The young leaves, flower buds and berries of black currant carry strongly
odoriferous glandular trichomes giving the plant a characteristic smell.
An extract for use in flavors and fragrances has been marketed since the
early 1960s as 'Bourgeons de Cassis'. It has a distinctive aroma with
a fresh top note, an intensely cat urine-like nuance and a strong fruity
background. Latrasse et al. in 1982 identified 4-methoxy-2-methylbutan-2-thiol
as an important trace constituent of the black currant aroma [83] [84].
Moreover, Nishimura et al. have demonstrated the occurrence of a number
of hydroxy nitriles in blackcurrant buds absolute, i.e. 2-cyanobutan-3-ol,
2-cyano-(Z)-2-buten-1-ol and 2-cyano-(E)-2-buten-1-ol [211].
Winter currant, a close relative to black currant, has the same olfactory
characteristics. It is a native of the mountainous regions in California
and Mexico, but is now grown in many temperate zones as an ornamental
plant. In the photo on the right, the glandular hairs are just visible
on the flower buds. Winter currant blooms in the early springtime. Where
the bushes form dense stands on sunny slopes, the air may be heavy with
their distinctive scent, which is also dominated by 4-methoxy-2-methylbutan-2-thiol
[210].
A black currant-like note is present in other plants too, e.g. in the
leaves of the South African buchu.